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ChemInform Abstract: Ruthenium-Catalyzed Oxidative Dearomatization of Phenols to 4-(tert-Butylperoxy)cyclohexadienones: Synthesis of 2-Substituted Quinones from p-Substituted Phenols.

โœ Scribed by Shun-Ichi Murahashi; Noriko Miyaguchi; Shinji Noda; Takeshi Naota; Akiko Fujii; Yasutaka Inubushi; Naruyoshi Komiya


Publisher
John Wiley and Sons
Year
2012
Weight
50 KB
Volume
43
Category
Article
ISSN
0931-7597

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Free-Radical Oxidation of para-Substituted Phenols by Hypervalent tert-Butylperoxyiodane and tert-Butyl Hydroperoxide: Synthesis of 4-(tert-Butylperoxy)-2,5-cyclohexadien-1-ones. -The selective radical oxidation of phenolic compounds by tert-butylperoxyiodane, which undergoes homolytic cleavage of