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ChemInform Abstract: Ruthenium-Catalyzed Cycloisomerization of 1,6-Enynes Initiated by C—H Activation.

✍ Scribed by Barry M. Trost; F. Dean Toste

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ruthenium-Catalyzed
ChemInform Abstract: Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex.
✍ C. SLUGOVC; K. MEREITER; E. ZOBETZ; R. SCHMID; K. KIRCHNER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.