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ChemInform Abstract: Ru-Catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-Hybrid Ligand.

✍ Scribed by Fusheng Bie; Yuehui Li; Weiguo Cao; Christian A. Sanboval

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201017073

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Readily available chiral hybrid NH 2 /tetrazole ligand [(S)-TEA, 1] in combination with Ru-BINAP or Ru-DIOP complexes catalyzes the asymmetric hydrogenation of a number of simple ketones with moderate enantioselectivity (up to 72% ee). The tetrazole functionality results in reversal of the typically

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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