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ChemInform Abstract: Rhodium-Catalyzed Asymmetric Transfer Hydrogenation of Aryl Alkyl Ketones Employing Ligands Derived from Amino Acids.

✍ Scribed by Jenny Wettergren; Alexey B. Zaitsev; Hans Adolfsson

Publisher: John Wiley and Sons
Year: 2008
Weight: 36 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200815072

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## Abstract Amino acid based thioamides, hydroxamic acids, and hydrazides have been evaluated as ligands in the rhodium‐catalyzed asymmetric transfer hydrogenation of ketones in 2‐propanol. Catalysts containing thioamide ligands derived from L‐valine were found to selectively generate the product w