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ChemInform Abstract: Ring Opening SN2′ Reactions of 1,4,5,8-Diepoxy-1,4,5,8-tetrahydroanthracenes by Organolithium Reagents.

✍ Scribed by O. ARJONA; M. LEON; J. PLUMET

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199828124

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✦ Synopsis

Ring

Opening S N 2' Reactions of 1,4,5,8-Diepoxy-1,4,5,8tetrahydroanthracenes by Organolithium Reagents.

-The nucleophilic opening of the oxygen bridges in diepoxytetrahydroanthracenes such as (I) with organolithium reagents is described. The dependence of the product selectivity on the excess and the nature of the reagents is discussed in detail. -(ARJONA, O.;

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