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ChemInform Abstract: Ring Opening of Phenylaziridines with Allylsilanes.

✍ Scribed by M.-R. SCHNEIDER; A. MANN; M. TADDEI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Ring Opening of Phenylaziridines with Allylsilanes.

-The title reaction gives regioselectively amino olefinic products, in most cases together with pyrrolidines. The latter are easily transformable to the former. If the solvent CH2Cl2 is changed to toluene, product (XVI) is formed exclusively. The fact that it is also identified in the absence of any silane reveals that toluene is an excellent nucleophile for ring-opening of activated phenylaziridines. -

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