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ChemInform Abstract: Ring-Opening of N-Tosyl Aziridines by 2-Lithiodithianes.

✍ Scribed by W. HOWSON; H. M. I. OSBORN; J. SWEENEY

Book ID: 112025630
Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199604069

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Preparation and Ring-Opening Reactions of N-Diphenylphosphinyl Vinyl Aziridines. -LDA-Lithiation of allyl bromide (I) followed by ZnCl2 generates α -bromo allyllithium which reacts with phosphinyl aldimines to form mainly trans-or cis-aziridines depending on the substituent R. The arylated trans-der