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ChemInform Abstract: Ring-Opening Hydrofluorination of 2,3- and 3,4-Epoxy Amines by HBF4·OEt2: Application to the Asymmetric Synthesis of (S,S)-3-Deoxy-3-fluorosafingol.

✍ Scribed by Alexander J. Cresswell; Stephen G. Davies; James A. Lee; Melloney J. Morris; Paul M. Roberts; James E. Thomson

Publisher: John Wiley and Sons
Year: 2011
Weight: 33 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201137053

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✦ Synopsis

Abstract

The reaction allows a simple, efficient, and highly stereoselective (< 98% d.e.) access to synthetically and biologically important fluorohydrins.

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