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ChemInform Abstract: Rhodium(I)-Catalyzed Enantioselective 1,4-Addition of Nucleophilic Silicon.

✍ Scribed by Christian Walter; Roland Froehlich; Martin Oestreich

Publisher
John Wiley and Sons
Year
2009
Weight
58 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Rhodium(I)-Catalyze
ChemInform Abstract: Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives.
✍ Tobias Seiser; Nicolai Cramer πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 73 KB πŸ‘ 1 views

## Abstract A C~aryl~β€”Si bond activation and 1,4‐Si shift of unactivated tetraorganylsilanes is readily achieved in the presence of chiral Rhβ€”difluorphos complex to give silylmethylindanols, e.g. (II), in good stereoselectivities (up to 99% e.e.