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ChemInform Abstract: Rhodium-Catalyzed Silylformylation of Acetylenic Bonds: Its Scope and Mechanistic Considerations.

โœ Scribed by I. MATSUDA; Y. FUKUTA; T. TSUCHIHASHI; H. NAGASHIMA; K. ITOH

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
29
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Intramolecular Silylformylation of Alkenes. -For the first time the silylformylation of alkenes is described. In every case the diastereomeric aldehydes are the major products. Small amounts of the diastereomeric hydrosilylation products are the only by-products. -(LEIGHTON,