ChemInform Abstract: Rhodium-Catalyzed Intermolecular Silylcarbamoylation of Acetylenic Bonds.

✍ Scribed by Isamu Matsuda; Kiyoshi Takeuchi; Kenji Itoh

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199926067

✦ Synopsis

Rhodium-Catalyzed Intermolecular Silylcarbamoylation of Acetylenic Bonds. -The formation of α,β-unsaturated amides (V) is readily achieved by a four-component one-pot silylcarbamoylation of alkynes (I) in the presence of catalytic amounts of Rh(0). -(MATSUDA, ISAMU; TAKEUCHI,