ChemInform Abstract: Rhodium-Catalyzed Functionalization of Sterically Hindered Alkenes.
β Scribed by Thomas Gendrineau; Jean-Pierre Genet; Sylvain Darses
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 45 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Rhodium-Catalyzed Intramolecular Silylformylation of Alkenes. -For the first time the silylformylation of alkenes is described. In every case the diastereomeric aldehydes are the major products. Small amounts of the diastereomeric hydrosilylation products are the only by-products. -(LEIGHTON,
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## Synthesis of Sterically Hindered Esters via Titanium Catalyzed Transesterification. -The alcoholysis of a variety of functionalized carboxylic esters with enantiopure menthol is easily achieved in the presence of titanium(IV) ethoxide as catalyst.