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ChemInform Abstract: Rhodium-Catalyzed Enantioselective Hydroboration of Alkenylboronic Esters with Catecholborane.

✍ Scribed by C. WIESAUER; W. WEISSENSTEINER

Book ID
112032043
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
27
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Hydroboration Reaction
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✍ Siphamandla W. Hadebe; Ross S. Robinson πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 133 KB πŸ‘ 1 views

## Abstract Rhodium‐catalyzed hydroboration of 1‐octene and __trans__‐4‐octene with sulfur‐ and nitrogen analogues of catecholborane are demonstrated with the use of in situ ^11^B NMR spectroscopy. Our study shows that the sulfur‐ and nitrogen analogues are significantly less prone to disproportion