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ChemInform Abstract: Rhodium-Catalyzed (E)-Selective Cross-Dimerization of Terminal Alkynes.

✍ Scribed by Takashi Katagiri; Hayato Tsurugi; Tetsuya Satoh; Masahiro Miura

Publisher: John Wiley and Sons
Year: 2008
Weight: 32 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200847057

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Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.