ChemInform Abstract: Rhodium-Catalyzed Carbothiolation Reaction of 1-Alkylthio-1-alkynes.
β Scribed by Mieko Arisawa; Yui Igarashi; Yoko Tagami; Masahiko Yamaguchi; Chizuko Kabuto
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 51 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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MAO-Catalyzed Allylzirconation of 1-Alkynes. -Hydrozirconation of the allene (I) followed by Et3Al catalyzed reaction with ethynylbenzene is found to result in selective formation of the heptadiene (III). However, using methoxyaluminoxane (MOA) as catalyst gives a remarkably enhanced regioselectivi