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ChemInform Abstract: Remote Asymmetric Induction in Organocopper Conjugate Additions to 3- Ketoacrylates.

โœ Scribed by L. F. CAPTAIN; X. XIA; D. C. LIOTTA


Book ID
112038562
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Remote Asymmetric I
โœ Eugene Ghera; Victoria Kleiman; Alfred Hassner ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB

Remote Asymmetric Induction in Michael Additions of Allylic Sulfones. -A new pathway of remote asymmetric induction in Michael reactions involving allylic ฮฑ-phenylsulfonyl carbanions in chiral donors is reported. The transmission of asymmetry is found to depend on the presence of an aromatic nucleu