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ChemInform Abstract: Remote Asymmetric Induction in Michael Additions of Allylic Sulfones.

✍ Scribed by Eugene Ghera; Victoria Kleiman; Alfred Hassner

Book ID
101886404
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Remote Asymmetric Induction in Michael Additions of Allylic Sulfones.

-A new pathway of remote asymmetric induction in Michael reactions involving allylic Ξ±-phenylsulfonyl carbanions in chiral donors is reported. The transmission of asymmetry is found to depend on the presence of an aromatic nucleus bound to the chiral center of the N-substituent in the donors. The change from phenyl to naphthyl improves the diastereocontrol of the reaction, whereas with cyclohexyl equal amounts of two diastereomers are formed.

-(GHERA, EUGENE; KLEIMAN, VICTORIA; HASSNER,

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v