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ChemInform Abstract: Remarkable Catalytic Activity of Me3Ga in the Alkylation of Hetero-Substituted Epoxides with Alkynyllithiums.

✍ Scribed by Takashi Ooi; Junko Morikawa; Hayato Ichikawa; Keiji Maruoka

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199943060

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Highly Efficient Alkylation of Epoxides with R 3 Al/H 2 O Systems Based on the Double Activation of Epoxy Oxygens. -Trialkylaluminum reagents [cf (II)] modified with substoichiometric amounts of water are found to be superior for the alkylative ring opening of epoxides such as (I) and (VI). Bidenta