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ChemInform Abstract: Regioselective Suzuki—Miyaura Reactions of the Bis(triflate) of 1,2,3,4-Tetrahydro-9,10-dihydroxyanthracen-1-one.

✍ Scribed by Ghazwan A. Salman; Ahmed Mahal; Mohanad Shkoor; Munawar Hussain; Alexander Villinger; Peter Langer

Book ID
102054830
Publisher
John Wiley and Sons
Year
2011
Weight
32 KB
Volume
42
Category
Article
ISSN
0931-7597

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Regioselective Suzuki–Miyaura reactions
Regioselective Suzuki–Miyaura reactions of the bis(triflate) of 1,2,3,4-tetrahydro-9,10-dihydroxyanthracen-1-one
✍ Ghazwan A. Salman; Ahmed Mahal; Mohanad Shkoor; Munawar Hussain; Alexander Villi 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 513 KB

The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflate) of 1,2,3,4-tetrahydro-9,10dihydroxyanthracen-1-one afforded various aryl-substituted 1,2,3,4-tetrahydroanthracen-1-ones. The reactions proceeded with very good site-selectivity in favour of position 10, due to electronic