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ChemInform Abstract: Regioselective Ring-Closing Metathesis on Terpenoid Acrylates and Acrylamides.

✍ Scribed by Yanming Du; David F. Wiemer


Book ID
101920164
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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Regioselective ring-closing metathesis o
✍ Yanming Du; David F Wiemer πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 104 KB

A series of acrylate esters was prepared by treatment of representative terpenoid aldehydes with allyl or vinyl magnesium bromide followed by reaction with acryloyl chloride. In all cases, ring-closing metathesis (RCM) resulted in regioselective formation of unsaturated lactones through metathesis o