## Abstract Highly substituted 1,2โallenyl ketones can be easily and efficiently prepared from organometallic reagents and readily available 2โ(1โalkynyl)โ2โalkenโ1โones. The synthetic application of 1,2โallenyl ketone products was also showcased by palladiumโcatalyzed further transformation.
ChemInform Abstract: Regioselective Addition of Organometallic Reagents to 2-(1-Alkynyl)-2-alken-1-ones for an Efficient Synthesis of Substituted 1,2-Allenyl Ketones.
โ Scribed by Xiuzhao Yu; Junliang Zhang
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 59 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
The allenyl ketones are useful synthons for tetrasubstituted allenes and highly substituted furans.
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