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ChemInform Abstract: Regio- and Stereocontrol in Rhenium-Catalyzed Transposition of Allylic Alcohols.

โœ Scribed by Aaron T. Herrmann; Tatsuo Saito; Craig E. Stivala; Janine Tom; Armen Zakarian


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: 1,3-Transposition o
โœ J. JACOB; J. H. ESPENSON; J. H. JENSEN; M. S. GORDON ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

1,3-Transposition of Allylic Alcohols Catalyzed by Methyltrioxorhenium. -The kinetics and theoretical calculations of the 1,3-rearrangement of allylic alcohols with MeReO 3 catalyst to generate the more stable isomer are studied. The direction of the equilibrium is largely influenced by the nature o