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ChemInform Abstract: Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds.

✍ Scribed by Nicolas Miquel; Gilles Doisneau; Jean-Marie Beau

Publisher: John Wiley and Sons
Year: 2001
Weight: 37 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200113206

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Reductive Samariation of Anomeric 2-Pyri

Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds

✍ Nicolas Miquel; Gilles Doisneau; Jean-Marie Beau 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 116 KB 👁 2 views

Reductive Samariation of Anomeric 2-Pyri

Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds

✍ Nicolas Miquel; Gilles Doisneau; Jean-Marie Beau 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

on the occasion of his 62nd birthday A direct method for the synthesis of C-glycosyl compounds derived from neutral hexoses was recently developed by our group. This procedure, which consists in the reductive samariation of anomeric 2-pyridyl sulfones in the presence of carbonyl compounds (Barbier p