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Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds

โœ Scribed by Nicolas Miquel; Gilles Doisneau; Jean-Marie Beau


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
116 KB
Volume
112
Category
Article
ISSN
0044-8249

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Reductive Samariation of Anomeric 2-Pyri
โœ Nicolas Miquel; Gilles Doisneau; Jean-Marie Beau ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 115 KB

on the occasion of his 62nd birthday A direct method for the synthesis of C-glycosyl compounds derived from neutral hexoses was recently developed by our group. This procedure, which consists in the reductive samariation of anomeric 2-pyridyl sulfones in the presence of carbonyl compounds (Barbier p