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ChemInform Abstract: Reductive Cleavage of the Se—Se Bond in Diselenides by the Sm/HgCl2 System: Formation and Reactions of Samarium Selenolates.

✍ Scribed by Lei Wang; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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Reductive cleavage of the Se–Se bond in
Reductive cleavage of the Se–Se bond in diselenides by the Sm/HgCl2 system: Formation and reactions of samarium selenolates
✍ Lei Wang; Yongmin Zhang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

Treatment of diaryl diselenides and dialkyl diselenides with metallic samarium and mercury (II) chloride in tetrahydrofuran conveniently gave samarium arylselenolates and alkylselenolates. These "living" species reacted with acyl chlorides, acid anhydrides, methyl chloroformate, organic halides, epo