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ChemInform Abstract: Reductive Alkylation of Nitrobenzene Promoted by Zinc and Tin in Protic Solvents.

โœ Scribed by Lothar W. Bieber; Rosenildo C. da Costa; Margarete F. da Silva


Book ID
101904419
Publisher
John Wiley and Sons
Year
2000
Weight
27 KB
Volume
31
Category
Article
ISSN
0931-7597

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Reductive alkylation of nitrobenzene pro
โœ Lothar W. Bieber; Rosenildo C. da Costa; Margarete F. da Silva ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 179 KB

Barbier-type organometallic reactions of nitrobenzene with organic halides in protic solvents produce directly N,N-dialkylanilines. With allyl bromide, best yields are obtained using zinc in an aqueous monobasic sodium phosphate solution in the presence of cuprous iodide or tin in methanol. The latt

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Reductive-Alkylation and Aromatic Coupling Reactions of 1,4-Benzoquinone Derivatives Promoted by Ethylaluminum Dichloride. -A new aromatic coupling reaction is observed for quinones (I), (IV) and (XI) yielding alkoxyphenyl dimers in moderate to good yields. The other quinones studied give 4-ethoxyp