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ChemInform Abstract: Reductive-Alkylation and Aromatic Coupling Reactions of 1,4-Benzoquinone Derivatives Promoted by Ethylaluminum Dichloride.

✍ Scribed by Vitor F. Ferreira; Francis J. Schmitz


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Reductive-Alkylation and Aromatic Coupling Reactions of 1,4-Benzoquinone Derivatives Promoted by Ethylaluminum Dichloride.

-A new aromatic coupling reaction is observed for quinones (I), (IV) and (XI) yielding alkoxyphenyl dimers in moderate to good yields. The other quinones studied give 4-ethoxyphenols with no regioselectivity. Simple 1,6-reduction products are also isolated in some cases such as (Xc). -(FERREIRA, VITOR


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