ChemInform Abstract: Rearrangement of the Intermediate 1,4-Biradicals in Photocycloaddition of Cyclohex-2-enones to Alkenes.
β Scribed by Ralf Constien; Bernd Kisilowski; Lars Meyer; Paul Margaretha
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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The Beckmann Rearrangement of Cyclohex-2-enone Oximes. Synthesis of 4, 5-Diphenyl-2,3,4,5-tetrahydro-1H-azepin-2-one. -The title compound (VI), which is an intermediate for the preparation of certain pesticides, can be prepared from both isomeric oximes (IV) and (V). In contrast, only the syn oxime
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