ChemInform Abstract: Rearrangement of Oxaspiroheptanes to Cyclohexanones Mediated by Lithium Iodide.
β Scribed by Didier Bouyssi; Marcello Cavicchioli; Sylvie Large; Nuno Monteiro; Genevieve Balme
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Stereochemistry of Enantioselective Deprotonation of 4-Substituted Cyclohexanones by Chiral Bidentate Lithium Amides. -Enantioselective deprotonation of 4-substituted cyclohexanones using chiral lithium amide bases such as (I) in the presence of excess trimethylsilyl chloride results in format
## Abstract Rearrangement of the pyranβbased aryl enol ethers proceeds with nearly complete diastereoselectivity affording the (E)βtrans products, regardless whether (E)β or (Z)βsubstrates are being used.