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ChemInform Abstract: Reactivity of Nucleophilic Uracil Derivatives.

✍ Scribed by G. GRANGIER; D. J. AITKEN; D. GUILLAUME; A. TOMAS; B. VIOSSAT; H.-P. HUSSON

Book ID
112021867
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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Nucleophilic Reactivity of N-Phosphorylated Ethyleneimine. -Whilst the diesters of the title compound (I) are unreactive towards alkylating agents, the corresponding ionic monoesters (II) undergo facile N-methylation with MeI, followed by opening at the aziridinium ring by the iodide ion (β†’ (IV)).