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ChemInform Abstract: Nucleophilic Reactivity of N-Phosphorylated Ethyleneimine.

✍ Scribed by C. LE ROUX; A. M. MODRO; T. A. MODRO

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Nucleophilic Reactivity of N-Phosphorylated Ethyleneimine.

-Whilst the diesters of the title compound (I) are unreactive towards alkylating agents, the corresponding ionic monoesters (II) undergo facile N-methylation with MeI, followed by opening at the aziridinium ring by the iodide ion (β†’ (IV)).

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