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ChemInform Abstract: Reactivity and Rearrangements of Dialkyl- and Diarylvinylsulfonium Salts with Indole-2- and Pyrrole-2-carboxaldehydes.

✍ Scribed by Yufeng Wang; Weihong Zhang; Vicent J. Colandrea; Leslie S. Jimenez

Book ID
101890441
Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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Reactivity and rearrangements of dialkyl
Reactivity and rearrangements of dialkyl- and diarylvinylsulfonium salts with indole-2- and pyrrole-2-carboxaldehydes
✍ Yufeng Wang; Weihong Zhang; Vincent J Colandrea; Leslie S Jimenez πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 742 KB

Various dialkyl-and diarylvinylsulfonium salts react with indole-2carboxaldehydes in the presence of sodium hydride and sodium azide to form tricyclic azido alcohols analogous to 2. With pyrrole-2-carboxaldehyde, [2,3] sigrnatropic and other rearrangements occur except in the case of diphenylvinylsu