ChemInform Abstract: Cobalt-Mediated [2 + 2 + 2] Cycloaddition of Alkynyl Boronates to Indole and Pyrrole Double Bonds.
β Scribed by Sabine Amslinger; Corinne Aubert; Vincent Gandon; Max Malacria; Elisa Paredes; K. Peter C. Vollhardt
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 41 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Improvement of the Diastereoselectivity of the Cobalt-Mediated [2 + 2 + 2] Cycloaddition of Substituted Linear Enediynes. -Substituting the terminal triple bond or the double bond in the enediynes (I) with ester, phosphine oxide or sulfoxide groups improves the level of diastereoselectivity in the
## Abstract Only one regioisomer is obtained with an excellent (E) selectivity.