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ChemInform Abstract: Reactions of t-Butylphosphine—Borane with Various Electrophiles and Synthesis of Optically Active t-Butylmethylphosphine—Borane.

✍ Scribed by Nobuhiko Oohara; Tsuneo Imamoto


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
33
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of Sphinganine by Means of Modified Asymmetric Borane Reduction. -A modified asymmetric borane reduction of the ester (I) and the related silyl ether (V) are described. Thus, reduction of the ester yields mainly the threo compound, whereas the silyl ether affords the desir