The reactions of Lawesson's reagent 1a and its 4-ethoxy homologue 1b with triethyl-and triphenyl(alkoxy)plumbanes 2a,b and -(alkylthio)plumbanes 4a,b were studied. On the basis of these reactions, novel, advantageous methods of synthesizing S-triethyl and triphenylplumbyl derivatives of aryldithio-a
ChemInform Abstract: Reactions of Dithioxo-1,3,2λ5,4λ5-dithiadiphosphetanes with Triorganolead Derivatives.
✍ Scribed by I. S. NIZAMOV; V. A. KUZNETZOV; E. S. BATYEVA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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New antimony(III) derivatives of dithiophosphonic and trithiophosphoric acids 3a-c and 5 were obtained by the reactions of Lawesson's reagent 1a, its homologue 1b, and the isobutyl homologue of Davy's reagent 4 with antimony(III) alkoxides 2a-c.
S-Arsenic(III) and arsenic(V) derivatives of aryldithiophosphonic, aryltrithiophosphonite, and aryl(amido)dithiophosphonic acids 3a-c, 5, 7, and 9a-c were obtained by the reactions of 2,4-diaryl-1,3,2,4-dithiadiphosphetane-2,4-disulfides 1a,b with O-isobutyl arsinite 2a, O,O-dimethylphosphonites 2b,