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ChemInform Abstract: Reactions of Complex Ligands. Part 83. Photochemical Activation of (α-exo-Alkylidene-2-oxacyclopentylidene)chromium Complexes for Benzannulation.

✍ Scribed by B. WEYERSHAUSEN; K. H. DOETZ

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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Photochemical Activation of (α-exo-Alkyl
Photochemical Activation of (α-exo-Alkylidene-2-oxacyclopentylidene)chromium Complexes for Benzannulation
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2,3-Dihydro-5-benzofuranols are synthesized by photo-2 and 3 with a series of terminal and symmetrical or unsymmetrical internal alkynes. No benzannulation reaction, chemical benzannulation of pentacarbonyl[(5-methylene or 5-benzylidene)-2-oxacyclopentylidene]chromium complexes however, is observed

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