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ChemInform Abstract: Reactions of 21-Acetoxy-16α,17α-epoxypregn-4-ene-3,20- dione with Nitrogen-Containing Nucleophilic Agents.

✍ Scribed by J. PROTIVA; NGUYEN THI THU HUONG NGUYEN THI THU HUONG; J. URBAN; E. KLINOTOVA


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of 6α-Met
✍ I. S. LEVINA; A. V. KAMERNITSKII 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Synthesis of 6α-Methyl-16α,17α-cyclohexanoprogesterone via γ-Methylenation of 16α,17. alpha.-Cyclohexanopregn-4-ene-3,20-dione. -An improved synthetic way to the title cyclohexanoprogesterone (IV) is presented. The introduction of the 6α-methyl group is achieved by regioselective γ-methylenation of