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ChemInform Abstract: Reactions of 2-Unsubstituted 1H-Imidazole 3-Oxides with Heterocumulenes and Dimethyl Acetylenedicarboxylate.

✍ Scribed by Grzegorz Mloston; Tomasz Gendek; Heinz Heimgartner

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Straightforward Acc
ChemInform Abstract: Straightforward Access to (Imidazol-2-yl)acetates by Reaction of 2-Unsubstituted Imidazole 3-Oxides with Dimethyl Acetylenedicarboxylate.
✍ Grzegorz Mloston; Marcin Jasinski; Heinz Heimgartner πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 28 KB

## Abstract The formation of the desired imidazoles is rationalized by a formal 1,3‐dipolar cycloaddition reaction followed by an oxaloyl cleavage of oxobutanoate intermediates (III).