ChemInform Abstract: Reactions of 2-Polyfluoroalkylchromones with Aliphatic Diamines.
β Scribed by V. Ya. Sosnovskikh; V. A. Kutsenko
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Reactions of 2-Polyfluoroalkylchromones with Aliphatic Diamines.
-The reaction of aliphatic 1,2-diamines with the title chromones affords 2,3-dihydro-1H-1,4-diazepines [cf.
(III), (VI)/(VII)] in good to excellent yields.
A similar reaction with 1,3-diaminopropane leads to trimethylenebis(hydroxyacetophenonimine) derivatives [cf.
(IX)] as a result of scission of the original chromones.
-(SOSNOVSKIKH, V. YA.;
π SIMILAR VOLUMES
Acylation of Aliphatic Diamines with Methyl Nitroacetate. -The first synthesis of N,N'-bis(nitroacetyl)diamines (cf. (IV), (VI)) by acylation of the corresponding diamines with nitroacetate (II) is accomplished. The reaction proceeds via isolable zwitterionic N-mononitroacetyl derivatives (cf. (III
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