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ChemInform Abstract: Acylation of Aliphatic Diamines with Methyl Nitroacetate.

โœ Scribed by I. M. LYAPKALO; S. L. IOFFE; YU. A. STRELENKO; V. A. TARTAKOVSKII

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Acylation of Aliphatic Diamines with Methyl Nitroacetate.

-The first synthesis of N,N'-bis(nitroacetyl)diamines (cf. (IV), (VI)) by acylation of the corresponding diamines with nitroacetate (II) is accomplished. The reaction proceeds via isolable zwitterionic N-mononitroacetyl derivatives (cf. (III)). -(LYAPKALO, I.

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