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ChemInform Abstract: Reaction of α-Amino Esters and α-Amino Ester Imines with Thiiranium Ion Intermediates. Application to the Synthesis of New Potential Aminopeptidase Inhibitors and Mechanistic Implications.

✍ Scribed by D. M. GILL; N. A. PEGG; C. M. RAYNER


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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A Novel Reaction of β,β'-Dihydroxy Acids or Esters with Vanadium(V) Trichloride Oxide. New Entry to the Stereoselective Synthesis of α-Fluoro-α,β-unsaturated Acids and Esters. -Deoxygenation of various aromatic dihydroxy acids and esters is optimally achieved upon treatment according to conditions