Nitroalkenes upon treatment with tributyltin hydride in the absence of any catalyst provide a new method for the reduction of 4 B-unsaturated nitrocompounds. Oxidative cleavage of the intermediate stannyl nitronates yielded carbonyl compounds in good yields.
ChemInform Abstract: Reaction of Tributyltin Hydride with α,β-Unsaturated N- Acyloxazolidinones.
✍ Scribed by M.-J. WU; C.-L. FU; T.-H. DUH; J.-Y. YEH
- Book ID
- 112036968
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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## 1999 hydroxycarboxylic acids hydroxycarboxylic acids (ether carboxylic acids) (acyclic compounds) and esters P 0280 ## 26 -081 Regio-and Diastereoselective Boron-Mediated Aldol Reactions of Chiral α,β,γ,δ-Unsaturated N-Acyloxazolidinones. -The established boron-mediated stereoselective aldol
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The reaction of a,fMuwsturated aldehydes and ketones with organotin hydrides have been studied intensively by Kuivils and Beumel 1,2 and by Valade and Pereyre 394. Where88 in the first reports on thin subject '9295 selective reduotion of the oarbonyl function (1) wae the only reaction observed, it h