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ChemInform Abstract: Reaction of Trialkyl(dibromomethyl)silanes or 1,2-Bis(dibromomethyl)benzene with Triorganomanganates. A Facile and Selective Synthesis of Alkenylsilanes and 1,2-Diaryl-1,2-dihydrobenzocyclobutenes.

✍ Scribed by Hirotada Kakiya; Hiroshi Shinokubo; Koichiro Oshima


Publisher
John Wiley and Sons
Year
2000
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one or Cyclohexanecarbaldehyde. -A survey of the selectivities shown by a number of organomanganate(II) reagents in the organic moiety transfer to substrates in two react