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ChemInform Abstract: Reaction of Thiobenzophenones with Norbornadiene: Unusual Formation of a Seven-Membered Cyclic Sulfide.

โœ Scribed by K. OKUMA; K. SHIKI; T. SHIROKAWA; K. KOJIMA; K. SHIOJI

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœ Michihito Sakura; Shinichi Ando; Atsushi Hattori; Katsuhiro Saito ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Reaction of Cyclohexa-1,2,3-triene with N,ฮฑ-Diphenylnitrone: Formation of Seven-Membered Cyclic Amines via Piradone Derivatives. -Treatment of the triflate (I) with CsF generates cyclohexa-1,2,3-triene, the smallest cyclic allene known to undergo fast dimerization. However, it can be trapped by dia