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ChemInform Abstract: Reaction of Methylcerium Reagent with Tertiary Amides: Synthesis of Saturated and Unsaturated Ketones from Tertiary Amides.

✍ Scribed by M. KUROSU; Y. KISHI

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides. -Base-promoted treatment of amides [cf. (I)] with triflic anhydride generates an iminium or imino triflate which reacts with an aminothiol directly to biologically interesting thiazolines. When optically pure cysteine