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ChemInform Abstract: Reaction of Metal Cyclopentadienides with 3,5-Bis(methylthio)-1,2- dithiolium Salts.

✍ Scribed by K. HARTKE; X.-P. POPP

Book ID
112023351
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
26
Category
Article
ISSN
0931-7597

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## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit