ChemInform Abstract: Reaction of 4-Bromobenzyl-3-methyl-1,2-oxazin-6-ones with Primary Aliphatic Amines. Synthesis and Structural Determination of New Oxazine and Isoxazole Derivatives.
β Scribed by M. BEBOT; P. COUDERT; F. LEAL; J. METIN; V. GAUMET; S. MAVEL; C. RUBAT; J. COUQUELET
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of 1,3,4-Oxadiazoles from Carboxylic Hydrazides and of 1,2-Oxazin-6-ones from Ξ±-(Hydroxyimino)carboxylic Esters with Keteneylidene Triphenylphosphorane. -A new route to oxadiazoles (III) via an untypical intermolecular Wittig olefination of hydrazide (I) and keteneylidene (II) is presented
Aminoenylesters. Part 1. A New Synthesis of 1,2,3,4-Tetrahydropyrimidines by Heterocyclic Anellation Reactions of Aminoenylesters with Primary Amines and Acetaldehyde. -A novel heterocyclization reaction is presented. Reaction of the methyl propiolate (I) with primary amines (II) gives the enamines