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ChemInform Abstract: Reaction of 1,3-Disubstituted Benzimidazolium Salts with Grignard Reagents and a Novel Synthetic Method for Aldehydes.

โœ Scribed by Z. SHI; H. GU


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Reaction of 1,3-Disubstituted Benzimidazolium Salts with Grignard Reagents and a Novel Synthetic Method for Aldehydes. -Reaction of 1,3-disubstituted benzimidazolium salts with Grignard reagents provides the corresponding 2-alkylated benzimidazolines (cf. ( III)), which smoothly hydrolyze furnishing the aldehydes (IV). -(SHI, Z.;


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ChemInform Abstract: Ultrasound Accelera
โœ T.-J. LU; S.-M. CHENG; L.-J. SHEU ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Ultrasound Accelerated Coupling Reaction of Grignard Reagents with 1,3-Dioxolanes of ฮฑ,ฮฒ-Unsaturated Aldehydes. -Allylic ethers are obtained in high yields by coupling of 1,3-dioxolanes of ฮฑ,ฮฒ-unsaturated aldehydes with Grignard reagents under mild conditions. The reaction, which is enhanced by ult