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ChemInform Abstract: Radical-Mediated Stereoselective Synthesis of (+)-Dihydrocanadensolide and (-)-3-epi-Dihydrocanadensolide from D-Xylose.

โœ Scribed by G. V. M. Sharma; T. Gopinath


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Syn
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Stereoselective Synthesis of 6-Deoxy and 3,6-Dideoxy-D-myo-inositol Precursors of Deoxy-myo-inositol Phosphate Analogues from D-Galactose. -The key step in the synthesis of the title compounds is the Ferrier rearrangement of pyranoside (II). Both resulting cyclohexanones (III) and (IV) can be trans