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ChemInform Abstract: Pushing the Limits of Steric Demand Around a Biaryl Axis: Synthesis of Tetra-ortho-Substituted Biaryl Naphthalenes.

✍ Scribed by Adam C. Glass; Sam Klonoski; Lev N. Zakharov; Shih-Yuan Liu

Publisher
John Wiley and Sons
Year
2011
Weight
38 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract **Incredible Bulk**: A series of N‐heterocyclic carbene catalysts (see picture) were prepared and evaluated in the Suzuki–Miyaura reaction. A variety of sterically encumbered tetra‐__ortho__‐substituted biaryl products were formed from unreactive aryl chlorides using the isopentyl‐subst